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Deactivation features related to the p-xylene oxidation mechanism over Pd catalysts

Paper ID Volume ID Publish Year Pages File Format Full-Text
51527 46846 2009 5 PDF Available
Title
Deactivation features related to the p-xylene oxidation mechanism over Pd catalysts
Abstract

The total oxidation of p-xylene over two commercial metal-supported Pd catalysts is examined. The evolution of the process showed the following trends: abrupt drop of the main reaction rate below 280 °C; steeper decrease over the range 290–320 °C, and no noticeable change at higher temperature. The kinetic analysis gives evidence about change of the apparent activation energy in the different temperature regions. The observed phenomena are associated with the non-uniformity of the catalyst properties. Reaction mechanism is suggested assuming contribution of surface sites of different adsorption strength. The conditions determining stationary or non-stationary behavior of the reaction system are discussed.

Keywords
Xylene oxidation; Pd catalyst; Mechanism; Kinetics
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Deactivation features related to the p-xylene oxidation mechanism over Pd catalysts
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Publisher
Database: Elsevier - ScienceDirect
Journal: Catalysis Communications - Volume 10, Issue 7, 10 March 2009, Pages 1034–1038
Authors
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Subjects
Physical Sciences and Engineering Chemical Engineering Catalysis
Get Full-Text Now
Don't Miss Today's Special Offer
Price was $35.95
You save - $31
Price after discount Only $4.95
100% Money Back Guarantee
Full-text PDF Download
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