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Tungstophosphoric acid (H3PW12O40) catalyzed oxidation of organic compounds with NaBrO3

Paper ID Volume ID Publish Year Pages File Format Full-Text
51536 46846 2009 5 PDF Available
Title
Tungstophosphoric acid (H3PW12O40) catalyzed oxidation of organic compounds with NaBrO3
Abstract

The oxidation of organic compounds by NaBrO3 under heteropoly acid catalysis in aqueous acetonitrile at room temperature has been studied. Primary and secondary aromatic alcohols are converted to aldehydes and ketones, alkyl arenes and sulfides oxidized to corresponding ketones and sulfoxide, respectively. In contrary, thiols undergo oxidative coupling reactions to give disulfides. The reaction was carried out in various solvents or under solvent free conditions. The reaction exhibited better results in terms of the yield and rate in H2O/CH3CN.

Keywords
Oxidation of organic compounds; Heteropoly acid; NaBrO3
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Tungstophosphoric acid (H3PW12O40) catalyzed oxidation of organic compounds with NaBrO3
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Publisher
Database: Elsevier - ScienceDirect
Journal: Catalysis Communications - Volume 10, Issue 7, 10 March 2009, Pages 1074–1078
Authors
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Subjects
Physical Sciences and Engineering Chemical Engineering Catalysis
Get Full-Text Now
Don't Miss Today's Special Offer
Price was $35.95
You save - $31
Price after discount Only $4.95
100% Money Back Guarantee
Full-text PDF Download
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