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Selective oxidation of alcohols with molecular oxygen catalyzed by Ru/MnOx/CeO2 under mild conditions

Paper ID Volume ID Publish Year Pages File Format Full-Text
51540 46846 2009 4 PDF Available
Title
Selective oxidation of alcohols with molecular oxygen catalyzed by Ru/MnOx/CeO2 under mild conditions
Abstract

A manganese oxides supported on cerium(IV) oxide MnOx/CeO2 precatalyst by wetness impregnation with manganese(II) acetate and cerium(IV) oxide. A Ru/MnOx/CeO2 catalyst was prepared by wetness impregnation of MnOx/CeO2 precatalyst with aqueous solution of ruthenium(III) chloride. The Ru/MnOx/CeO2 catalyst has high catalytic activities for the oxidation of alcohols to the corresponding carbonyl compounds. Especially, the advantage of the present catalyst is the smooth oxidation of alcohols at 300 K under molecular oxygen atmosphere.

Keywords
Alcohol oxidation; Ru heterogeneous catalyst; Molecular oxygen; Mild conditions
First Page Preview
Selective oxidation of alcohols with molecular oxygen catalyzed by Ru/MnOx/CeO2 under mild conditions
Publisher
Database: Elsevier - ScienceDirect
Journal: Catalysis Communications - Volume 10, Issue 7, 10 March 2009, Pages 1095–1098
Authors
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Subjects
Physical Sciences and Engineering Chemical Engineering Catalysis