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Synthesis, characterization and catalytic properties of a highly stereoselective olefin metathesis catalyst

Paper ID Volume ID Publish Year Pages File Format Full-Text
51544 46846 2009 6 PDF Available
Title
Synthesis, characterization and catalytic properties of a highly stereoselective olefin metathesis catalyst
Abstract

The X-ray determination of a tungsten based complex allowed to definitively assign its structure and chemical formula to W(OC6H3PhC6H4)(OAr)(=CHC(CH3)3)Cl with Ar = 2,6-Ph2C6H3. This complex is a catalytic system which displays high metathesis activity and high stereoselectivity even for bulky functional olefins.

Keywords
Metathesis; Stereoselectivity; Carbenes; Homogeneous catalysis; Tungsten
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Synthesis, characterization and catalytic properties of a highly stereoselective olefin metathesis catalyst
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Publisher
Database: Elsevier - ScienceDirect
Journal: Catalysis Communications - Volume 10, Issue 7, 10 March 2009, Pages 1111–1116
Authors
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Subjects
Physical Sciences and Engineering Chemical Engineering Catalysis
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Price was $35.95
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