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Synthesis of dimethyl carbonate (DMC) from methanol and CO2 over Rh-supported catalysts

Paper ID Volume ID Publish Year Pages File Format Full-Text
51547 46846 2009 5 PDF Available
Title
Synthesis of dimethyl carbonate (DMC) from methanol and CO2 over Rh-supported catalysts
Abstract

The synthesis of dimethyl carbonate (DMC) from methanol and CO2 has been investigated using a vapor phase flow reactor system and in the presence of various Rh-supported catalysts. The effects of reaction conditions, supports, and promoters on catalyst performance were evaluated in terms of methanol conversion and DMC selectivity. The results show that DMC synthesis proceeds effectively at low temperatures (353–433 K), while at higher temperatures dimethyl ether (DME) is the predominant product. Loss of surface chloride results in substantial catalyst system deactivation.

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Synthesis of dimethyl carbonate (DMC) from methanol and CO2 over Rh-supported catalysts
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Publisher
Database: Elsevier - ScienceDirect
Journal: Catalysis Communications - Volume 10, Issue 7, 10 March 2009, Pages 1127–1131
Authors
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Subjects
Physical Sciences and Engineering Chemical Engineering Catalysis
Get Full-Text Now
Don't Miss Today's Special Offer
Price was $35.95
You save - $31
Price after discount Only $4.95
100% Money Back Guarantee
Full-text PDF Download
Online Support
Any Questions? feel free to contact us