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A synergistic effect in the combination of H2O2, FeAPO-5 and NaBr for selective oxidation of benzyl alcohols

Paper ID Volume ID Publish Year Pages File Format Full-Text
51595 46847 2011 4 PDF Available
Title
A synergistic effect in the combination of H2O2, FeAPO-5 and NaBr for selective oxidation of benzyl alcohols
Abstract

The H2O2/FeAPO-5/NaBr combination has been found to be active in the oxidation of benzyl alcohols. The remarkably different activity results obtained with the H2O2/FeAPO-5/NaBr, the H2O2/FeAPO-5 and the H2O2/NaBr confirm the existence of a strongly synergistic effect in the ternary reaction system of H2O2, FeAPO-5 and NaBr, leading to a significantly enhanced conversion of benzyl alcohols under mild reaction conditions.

Graphical abstractFigure optionsDownload full-size imageDownload as PowerPoint slideHighlights► The oxidation of benzyl alcohols was investigated with three reaction systems. ► Only 5–10% conversions were obtained with the H2O2/FeAPO-5 and the H2O2/NaBr. ► A synergistic effect from the H2O2/FeAPO-5/NaBr leads to 40–80% conversions. ►

Keywords
Selective oxidation; Benzyl alcohols; Hydrogen peroxide; FeAPO-5 molecular sieves; Sodium bromide
First Page Preview
A synergistic effect in the combination of H2O2, FeAPO-5 and NaBr for selective oxidation of benzyl alcohols
Publisher
Database: Elsevier - ScienceDirect
Journal: Catalysis Communications - Volume 16, Issue 1, 30 November 2011, Pages 225–228
Authors
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Subjects
Physical Sciences and Engineering Chemical Engineering Catalysis