fulltext.study @t Gmail

A practical innovative method for highly selective oxidation of alcohols in neat water using water-insoluble iron and manganese porphyrins as reusable heterogeneous catalysts

Paper ID Volume ID Publish Year Pages File Format Full-Text
51598 46847 2011 5 PDF Available
Title
A practical innovative method for highly selective oxidation of alcohols in neat water using water-insoluble iron and manganese porphyrins as reusable heterogeneous catalysts
Abstract

A novel heterogeneous method for clean and selective oxidation of alcohols to the aldehydes and ketones using tetrabutylammonium peroxomonosulfate (n-Bu4NHSO5) in neat water catalyzed by simple Fe (III) and Mn (III) meso-tetraphenylporphyrin as a water-insoluble catalyst has been developed. The oxidation system proceeds well in the absence of organic co-solvents and surfactants. The presence of an electron-donating group on the phenyl ring of benzyl alcohol increases the reactivity of substrate. The catalysts could easily be recycled and reused without noticeable loss of activity and the oxidant's by-product (n-Bu4NHSO4) could also be recycled.

Graphical abstractFigure optionsDownload full-size imageDownload as PowerPoint slideHighlights► Fe- and Mn-porphyrins catalyze highly selective alcohol oxidation in neat water. ► The reactions proceed well in the absence of organic co-solvents and surfactants. ► The porphyrin catalysts can be easily recycled and reused without loss of activity.

Keywords
Porphyrin; Oxidation; Alcohol; Water; Heterogeneous catalyst
First Page Preview
A practical innovative method for highly selective oxidation of alcohols in neat water using water-insoluble iron and manganese porphyrins as reusable heterogeneous catalysts
Get Full-Text Now
Don't Miss Today's Special Offer
Price was $35.95
You save - $31
Price after discount Only $4.95
100% Money Back Guarantee
Full-text PDF Download
Online Support
Any Questions? feel free to contact us
Publisher
Database: Elsevier - ScienceDirect
Journal: Catalysis Communications - Volume 16, Issue 1, 30 November 2011, Pages 240–244
Authors
, , ,
Subjects
Physical Sciences and Engineering Chemical Engineering Catalysis
Get Full-Text Now
Don't Miss Today's Special Offer
Price was $35.95
You save - $31
Price after discount Only $4.95
100% Money Back Guarantee
Full-text PDF Download
Online Support
Any Questions? feel free to contact us