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Model dioxovanadium(V) complexes through direct immobilization on polymer support, their characterization and catalytic activities

Paper ID Volume ID Publish Year Pages File Format Full-Text
51616 46848 2008 5 PDF Available
Title
Model dioxovanadium(V) complexes through direct immobilization on polymer support, their characterization and catalytic activities
Abstract

Dioxovanadium(V) complexes, K[VO2(sal-inh)(H2O)] and K[VO2(sal-bhz)(H2O)] (where H2sal-inh = Schiff base derived from salicylaldehyde and isonicotinoylhydrazide, and H2sal-bhz = Schiff base derived from salicylaldehyde and benzoylhydrazide) have been reacted with polymer bound imidazole (PS-im) to give polymer-supported complexes, abbreviated as PS-K[VO2(sal-inh)(im)] and PS-K[VO2(sal-bhz)(im)]. Characterization and catalytic potential of these complexes for the oxidative bromination of salicylaldehyde, oxidation of methyl phenyl sulfide and benzene using 30% H2O2 as an oxidant have been reported.

Keywords
Polymer support; Dioxovanadium(V) complexes; Catalysts; Oxidation reactions
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Model dioxovanadium(V) complexes through direct immobilization on polymer support, their characterization and catalytic activities
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Publisher
Database: Elsevier - ScienceDirect
Journal: Catalysis Communications - Volume 10, Issue 2, 15 November 2008, Pages 187–191
Authors
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Subjects
Physical Sciences and Engineering Chemical Engineering Catalysis
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