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Zn/Fe mixed oxide: Heterogeneous catalyst for the synthesis of dimethyl carbonate from methyl carbamate and methanol

Paper ID Volume ID Publish Year Pages File Format Full-Text
51660 46849 2010 4 PDF Available
Title
Zn/Fe mixed oxide: Heterogeneous catalyst for the synthesis of dimethyl carbonate from methyl carbamate and methanol
Abstract

A series of Zn–Fe–O mixed oxides were prepared for the synthesis of dimethyl carbonate (DMC) from methyl carbamate and methanol. X-ray diffraction revealed that zinc ferrite crystal phase appeared and changed with different Zn/Fe molar ratio. The DMC yield could reach 30.7% under suitable conditions. In addition, elemental chemical analysis and the reusability test indicated that these catalysts presented good stability.

Keywords
Dimethyl carbonate; Methyl carbamate; Methanol; Zn/Fe mixed oxide
First Page Preview
Zn/Fe mixed oxide: Heterogeneous catalyst for the synthesis of dimethyl carbonate from methyl carbamate and methanol
Publisher
Database: Elsevier - ScienceDirect
Journal: Catalysis Communications - Volume 11, Issue 5, 25 January 2010, Pages 430–433
Authors
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Subjects
Physical Sciences and Engineering Chemical Engineering Catalysis