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Selective dehydrosulfurization of 3-mercaptopropionic acid to acrylic acid on silicalite catalyst

Paper ID Volume ID Publish Year Pages File Format Full-Text
51666 46849 2010 4 PDF Available
Title
Selective dehydrosulfurization of 3-mercaptopropionic acid to acrylic acid on silicalite catalyst
Abstract

Dehydrosulfurization of 3-mercaptopropionic acid has been investigated in a fixed bed reactor using a silicalite catalyst in order to recover the hydrocarbon core. Under reductive conditions, acrylic acid was formed in high yield at 350 °C and atmospheric pressure as the desired product along the toxic H2S, whereas, carrying out the reaction in the presence of air, safer dihydrogenpolysulfides resulted as the co-product.

Keywords
Acrylic acid; 3-Mercaptopropionic acid; Acid catalysis; Dehydrosulfurization; Silicalite
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Publisher
Database: Elsevier - ScienceDirect
Journal: Catalysis Communications - Volume 11, Issue 5, 25 January 2010, Pages 456–459
Authors
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Subjects
Physical Sciences and Engineering Chemical Engineering Catalysis
Get Full-Text Now
Don't Miss Today's Special Offer
Price was $35.95
You save - $31
Price after discount Only $4.95
100% Money Back Guarantee
Full-text PDF Download
Online Support
Any Questions? feel free to contact us