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Peroxopolyoxometalate-based room temperature ionic liquid as a self-separation catalyst for epoxidation of olefins

Paper ID Volume ID Publish Year Pages File Format Full-Text
51669 46849 2010 6 PDF Available
Title
Peroxopolyoxometalate-based room temperature ionic liquid as a self-separation catalyst for epoxidation of olefins
Abstract

A new peroxopolyoxometalate-based room temperature ionic liquid (POM-RTIL) has been synthesized and used as catalyst for efficient epoxidation of various olefins. The RTIL catalyst was found to be well dissolved in the solvent (ethyl acetate) during the reaction, while it can self-separate from the reaction media at room temperature after the reaction completed, which made the recovery and reuse of the IL catalyst convenient. The POM-RTIL catalyst can be recycled for five times without significant loss of activity.

Keywords
Polyoxometalate; Epoxidation; Olefin; Ionic liquid; Self-separation
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Peroxopolyoxometalate-based room temperature ionic liquid as a self-separation catalyst for epoxidation of olefins
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Publisher
Database: Elsevier - ScienceDirect
Journal: Catalysis Communications - Volume 11, Issue 5, 25 January 2010, Pages 470–475
Authors
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Subjects
Physical Sciences and Engineering Chemical Engineering Catalysis
Get Full-Text Now
Don't Miss Today's Special Offer
Price was $35.95
You save - $31
Price after discount Only $4.95
100% Money Back Guarantee
Full-text PDF Download
Online Support
Any Questions? feel free to contact us