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Highly efficient asymmetric transfer hydrogenation of ketones in emulsions

Paper ID Volume ID Publish Year Pages File Format Full-Text
51671 46849 2010 4 PDF Available
Title
Highly efficient asymmetric transfer hydrogenation of ketones in emulsions
Abstract

Ru-TsDPEN (TsDPEN = N-(p-tolylsulfonyl)-1,2-diphenylethylenediamine) catalyzed asymmetric transfer hydrogenation of ketones in emulsions is reported for the first time. The new protocol provides markedly enhanced activity and enantioselectivities (up to 99% ee) as compared with results when performed either in an aqueous medium or in common organic solvents.

Keywords
Emulsion; Water; Asymmetric hydrogenation; Ketones
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Highly efficient asymmetric transfer hydrogenation of ketones in emulsions
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Publisher
Database: Elsevier - ScienceDirect
Journal: Catalysis Communications - Volume 11, Issue 5, 25 January 2010, Pages 480–483
Authors
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Subjects
Physical Sciences and Engineering Chemical Engineering Catalysis
Get Full-Text Now
Don't Miss Today's Special Offer
Price was $35.95
You save - $31
Price after discount Only $4.95
100% Money Back Guarantee
Full-text PDF Download
Online Support
Any Questions? feel free to contact us