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[Ru(salen)(NO)] complex encapsulated in mesoporous SBA-16 as catalyst for hydrogenation of ketones

Paper ID Volume ID Publish Year Pages File Format Full-Text
51686 46850 2008 4 PDF Available
Title
[Ru(salen)(NO)] complex encapsulated in mesoporous SBA-16 as catalyst for hydrogenation of ketones
Abstract

SBA-16 mesoporous silica with cubic Im3m structure was synthesized using Pluronic F127 poly(ethylene oxide)-poly(propylene oxide)-poly(ethylene oxide) triblock copolymer (EO106PO70EO106) and it blends with Pluronic P123 triblock copolymer (EO20PO70EO20) as supramolecular templates. The resulting material was used for encapsulating [Ru(salen)(NO)] complex and used in the hydrogenation of ketones to the corresponding alcohols. The pore entrance size of SBA-16 was precisely tailored by silylation with diphenyldichlorosilane to trap [Ru(salen)(NO)] complex in the cage of SBA-16. Small angle XRD, N2 sorption measurements, UV–Vis and FT-IR analysis evidences the structural integrity of mesoporous silica as well as the complex.

Keywords
[Ru(salen)(NO)] complex; Encapsulation; SBA-16; Hydrogenation; Ketones
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[Ru(salen)(NO)] complex encapsulated in mesoporous SBA-16 as catalyst for hydrogenation of ketones
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Publisher
Database: Elsevier - ScienceDirect
Journal: Catalysis Communications - Volume 10, Issue 1, 10 October 2008, Pages 45–48
Authors
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Subjects
Physical Sciences and Engineering Chemical Engineering Catalysis
Get Full-Text Now
Don't Miss Today's Special Offer
Price was $35.95
You save - $31
Price after discount Only $4.95
100% Money Back Guarantee
Full-text PDF Download
Online Support
Any Questions? feel free to contact us