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Unmodified chiral primary amino alcohol as a new ligand for enantioselective alkynylation of aldehydes

Paper ID Volume ID Publish Year Pages File Format Full-Text
51701 46850 2008 5 PDF Available
Title
Unmodified chiral primary amino alcohol as a new ligand for enantioselective alkynylation of aldehydes
Abstract

The unmodified available chiral amino alcohol 14 in combination with Ti(OiPr)4 was found to catalyze the reaction of an alkynylzinc reagent with various aldehydes to generate chiral propargylic alcohols with moderate to good yields and enantioselectivities.

Keywords
Amino alcohol; Asymmetric alkynylation; Phenylacetylene; Enantioselectivity; Propargylic alcohols
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Unmodified chiral primary amino alcohol as a new ligand for enantioselective alkynylation of aldehydes
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Publisher
Database: Elsevier - ScienceDirect
Journal: Catalysis Communications - Volume 10, Issue 1, 10 October 2008, Pages 113–117
Authors
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Subjects
Physical Sciences and Engineering Chemical Engineering Catalysis
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Price was $35.95
You save - $31
Price after discount Only $4.95
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Full-text PDF Download
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