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Palladium nanoparticles supported on amino functionalized metal-organic frameworks as highly active catalysts for the Suzuki–Miyaura cross-coupling reaction

Paper ID Volume ID Publish Year Pages File Format Full-Text
51711 46851 2011 5 PDF Available
Title
Palladium nanoparticles supported on amino functionalized metal-organic frameworks as highly active catalysts for the Suzuki–Miyaura cross-coupling reaction
Abstract

Well dispersed Pd nanoparticles supported on amino functionalized metal-organic frameworks MIL-53(Al)-NH2 (Al(OH)[H2N-BDC], H2N-BDC = 2-aminoterephthalic acid, MIL = Materials of Institut Lavoisier) were prepared using a direct anionic exchange approach and subsequent reduction with NaBH4. The Pd/MIL-53(Al)-NH2 catalyst exhibitted high activity and good stability for Suzuki–Miyaura cross-coupling reaction.

Graphical abstractFigure optionsDownload full-size imageDownload as PowerPoint slideHighlights► Palladium NPs supported on amino functionalized MIL-53(Al)-NH2 have been prepared. ► Palladium NPs stabilized by amine groups with a uniform size of ca. 3 nm. ► Palladium NPs exhibit high activity and good stability for Suzuki–Miyaura reaction.

Keywords
Metal-organic frameworks; Palladium nanoparticles; Amine; Suzuki–Miyaura coupling reaction
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Palladium nanoparticles supported on amino functionalized metal-organic frameworks as highly active catalysts for the Suzuki–Miyaura cross-coupling reaction
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Publisher
Database: Elsevier - ScienceDirect
Journal: Catalysis Communications - Volume 14, Issue 1, 25 October 2011, Pages 27–31
Authors
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Subjects
Physical Sciences and Engineering Chemical Engineering Catalysis
Get Full-Text Now
Don't Miss Today's Special Offer
Price was $35.95
You save - $31
Price after discount Only $4.95
100% Money Back Guarantee
Full-text PDF Download
Online Support
Any Questions? feel free to contact us