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Steric constraints on adsorption in heterogeneous catalytic reactions

Paper ID Volume ID Publish Year Pages File Format Full-Text
51751 46853 2008 4 PDF Available
Title
Steric constraints on adsorption in heterogeneous catalytic reactions
Abstract

The kinetics of heterogeneous catalytic reactions with participation of large molecules can be influenced by steric constraints on their adsorption. Using a generic model of alkane hydrogenolysis, the author presents Monte Carlo simulations explicitly illustrating that this effect may dramatically change the apparent reaction order in alkane. The predictions drawn are in good agreement with the results of numerous experimental studies performed on various metals.

Keywords
Kinetics; Surface chemical reactions; Hydrogenolysis; Alkanes; Hydrogen; Low index single crystal surfaces; Computer simulations
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Steric constraints on adsorption in heterogeneous catalytic reactions
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Publisher
Database: Elsevier - ScienceDirect
Journal: Catalysis Communications - Volume 9, Issue 14, 30 August 2008, Pages 2319–2322
Authors
,
Subjects
Physical Sciences and Engineering Chemical Engineering Catalysis
Get Full-Text Now
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Price was $35.95
You save - $31
Price after discount Only $4.95
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Full-text PDF Download
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