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Selective oxidation of p-nitrobenzyl alcohol to p-nitrobenzaldehyde with 10% Ni silica with 30% H2O2 in acetonitrile solvent

Paper ID Volume ID Publish Year Pages File Format Full-Text
51773 46853 2008 5 PDF Available
Title
Selective oxidation of p-nitrobenzyl alcohol to p-nitrobenzaldehyde with 10% Ni silica with 30% H2O2 in acetonitrile solvent
Abstract

p-Nitrobenzyl alcohol is oxidized to p-nitrobenzaldehyde with good selectivity using 30% H2O2 and 10% Ni/SiO2 as catalyst in acetonitirle, as refluxing solvent. A 95% conversion and single product are achieved. Using the same system, benzhydrol was selectively converted to benzophenone with 100% conversion. Cinnamyl alcohol, menthol and cyclohexanol were also converted to their corresponding aldehydes or ketones, but with less efficiency.

Keywords
Hydrogen peroxide; Ni–SiO2 catalyst; p-Nitrobenzyl alcohol; Oxidation
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Selective oxidation of p-nitrobenzyl alcohol to p-nitrobenzaldehyde with 10% Ni silica with 30% H2O2 in acetonitrile solvent
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Publisher
Database: Elsevier - ScienceDirect
Journal: Catalysis Communications - Volume 9, Issue 14, 30 August 2008, Pages 2417–2421
Authors
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Subjects
Physical Sciences and Engineering Chemical Engineering Catalysis
Get Full-Text Now
Don't Miss Today's Special Offer
Price was $35.95
You save - $31
Price after discount Only $4.95
100% Money Back Guarantee
Full-text PDF Download
Online Support
Any Questions? feel free to contact us