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Bismuth(III) nitrate pentahydrate: a stoichiometric reagent for microwave induced mild and highly efficient aerial oxidation of aromatic aldehydes under solvent-free conditions

Paper ID Volume ID Publish Year Pages File Format Full-Text
51810 46854 2008 5 PDF Available
Title
Bismuth(III) nitrate pentahydrate: a stoichiometric reagent for microwave induced mild and highly efficient aerial oxidation of aromatic aldehydes under solvent-free conditions
Abstract

Aromatic aldehydes possessing a wide variety of substituents were smoothly converted to carboxylic acids in excellent yields by stoichiometric bismuth(III) nitrate pentahydrate in presence of aerial oxygen in a microwave-oven under solvent-free conditions. The method is environmentally benign being solvent-free, operationally simple, highly chemoselective, employing no cumbersome work-up procedures, having wide general applicability, short reaction times, mild reaction conditions, large scale-ups and very good yields.

Keywords
Bismuth(III) nitrate pentahydrate; Aromatic aldehydes; Aerial oxidation; Solvent-free conditions; Carboxylic acids; Microwaves
First Page Preview
Bismuth(III) nitrate pentahydrate: a stoichiometric reagent for microwave induced mild and highly efficient aerial oxidation of aromatic aldehydes under solvent-free conditions
Publisher
Database: Elsevier - ScienceDirect
Journal: Catalysis Communications - Volume 9, Issue 15, 20 September 2008, Pages 2588–2592
Authors
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Subjects
Physical Sciences and Engineering Chemical Engineering Catalysis