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Ionic liquid (molten salt): Thermoregulated catalyst support for catalytic hydrosilylation process

Paper ID Volume ID Publish Year Pages File Format Full-Text
51882 46857 2008 3 PDF Available
Title
Ionic liquid (molten salt): Thermoregulated catalyst support for catalytic hydrosilylation process
Abstract

The high melting point molten organic salts N-alkylpyridinium hexafluorophosphates have been used as thermoregulated supports. The influence of the structure of the molten organic salts on hydrosilylation reactions has been investigated and it was found that the alkyl chains attached to the pyridinium have an impact on the catalytic activities and selectivities. Additionally, by using this kind of thermoregulated catalyst support, the catalyst phase is liquid phase under the reaction conditions, whereas the catalyst supported by molten organic salt is solid phase at room temperature, therefore, it can be reused simply by decantation.

Keywords
Thermoregulated; Hydrosilylation; Molten organic salt; N-alkylpyridinium hexafluorophosphate; Rh(PPh3)3Cl
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Ionic liquid (molten salt): Thermoregulated catalyst support for catalytic hydrosilylation process
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Publisher
Database: Elsevier - ScienceDirect
Journal: Catalysis Communications - Volume 9, Issue 13, 20 July 2008, Pages 2236–2238
Authors
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Subjects
Physical Sciences and Engineering Chemical Engineering Catalysis
Get Full-Text Now
Don't Miss Today's Special Offer
Price was $35.95
You save - $31
Price after discount Only $4.95
100% Money Back Guarantee
Full-text PDF Download
Online Support
Any Questions? feel free to contact us