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The decomposition of CCl4 into diphenyl carbonate over MClχ/SiMCM-41

Paper ID Volume ID Publish Year Pages File Format Full-Text
51922 46858 2008 5 PDF Available
Title
The decomposition of CCl4 into diphenyl carbonate over MClχ/SiMCM-41
Abstract

MClχ/SiMCM-41 was prepared by impregnation and its behaviors on the decomposition of CCl4 into diphenyl carbonate (DPC) were examined. The maximum DPC yield of 20.7% was obtained when ZnCl2 was supported on SiMCM-41 with 35% loading. ZnCl2/SiMCM-41 was characterized by XRD and N2 adsorption–desorption isotherms, and the characterized results showed that ZnCl2 was highly dispersed on SiMCM-41 and ZnCl2/SiMCM-41 had high BET surface area. The main reasons for ZnCl2/SiMCM-41 displaying the higher activity than any other MClχ/SiMCM-41 might be the zero ligands field stabilized energy (LFSE) and strong Lewis acid of Zn (II).

Keywords
Diphenyl carbonate; Phenol; CCl4; MClχ/MCM-41; CO2
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The decomposition of CCl4 into diphenyl carbonate over MClχ/SiMCM-41
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Publisher
Database: Elsevier - ScienceDirect
Journal: Catalysis Communications - Volume 9, Issue 7, 1 April 2008, Pages 1666–1670
Authors
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Subjects
Physical Sciences and Engineering Chemical Engineering Catalysis
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Don't Miss Today's Special Offer
Price was $35.95
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