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Kinetic study of oxidation of cyclohexanol using bimetallic iron–copper macrocyclic complex catalyst

Paper ID Volume ID Publish Year Pages File Format Full-Text
51932 46859 2008 6 PDF Available
Title
Kinetic study of oxidation of cyclohexanol using bimetallic iron–copper macrocyclic complex catalyst
Abstract

Commercial catalysts for oxidation of cyclohexanol to cyclohexanone are known to deactivate at high temperature with time. A macrocyclic FeCu complex covalently bonded to modified alumina support was prepared for oxidation of cyclohexanol using molecular oxygen. The catalyst was shown to be thermally stable and does not deactivate for atleast hundred hours of usage for oxidation of cyclohexanol. The reaction has been carried out using molecular oxygen without any solvent, coreactant or cocatalyst in the temperature range of 125–250 °C at 27 atm. An irreversible first order reaction mechanism has been proposed and optimal rate constants were determined.

Keywords
Cyclohexanol; Cyclohexanone; FeCu/Alumina; Oxidation; Kinetic study
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Kinetic study of oxidation of cyclohexanol using bimetallic iron–copper macrocyclic complex catalyst
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Publisher
Database: Elsevier - ScienceDirect
Journal: Catalysis Communications - Volume 10, Issue 3, 15 December 2008, Pages 285–290
Authors
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Subjects
Physical Sciences and Engineering Chemical Engineering Catalysis
Get Full-Text Now
Don't Miss Today's Special Offer
Price was $35.95
You save - $31
Price after discount Only $4.95
100% Money Back Guarantee
Full-text PDF Download
Online Support
Any Questions? feel free to contact us