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A study of the electrocatalytic oxidation of cyclohexanol on copper electrode

Paper ID Volume ID Publish Year Pages File Format Full-Text
51934 46859 2008 5 PDF Available
Title
A study of the electrocatalytic oxidation of cyclohexanol on copper electrode
Abstract

Electrocatalytic oxidation of cyclohexanol was investigated on copper electrode in alkaline solution. The process of oxidation involved and its kinetics were established by using cyclic voltammetry, chronoamperometry techniques as well as steady state polarization measurements. It has been found that in the course of an anodic potential sweep the electro-oxidation of cyclohexanol follows the formation of Cu (III) and is catalysed by this species through a mediated electron transfer mechanism. A mechanism based on the electrochemical generation of Cu (III) active sites and their subsequent consumption by the cyclohexanol in question was also investigated.

Keywords
Cyclohexanol; Electrocatalysis; Copper; Alkaline media
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A study of the electrocatalytic oxidation of cyclohexanol on copper electrode
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Publisher
Database: Elsevier - ScienceDirect
Journal: Catalysis Communications - Volume 10, Issue 3, 15 December 2008, Pages 295–299
Authors
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Subjects
Physical Sciences and Engineering Chemical Engineering Catalysis
Get Full-Text Now
Don't Miss Today's Special Offer
Price was $35.95
You save - $31
Price after discount Only $4.95
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