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Highly enantioselective epoxidation of styrene and α-methylstyrene catalyzed by new doubly-immobilized chiral (salen)Mn(III) catalysts

Paper ID Volume ID Publish Year Pages File Format Full-Text
51939 46859 2008 4 PDF Available
Title
Highly enantioselective epoxidation of styrene and α-methylstyrene catalyzed by new doubly-immobilized chiral (salen)Mn(III) catalysts
Abstract

A novel catalytic system, including the initial immobilization of a sulphonato-(salen)Mn(III) complex on two silica supports through the linkage of hydrogen bonding anchored on the 5,5′-positions of salen ring and the subsequent dispersion of supported catalysts into ionic liquid, was designed and applied in this work. These new doubly-immobilized chiral (salen)Mn(III) catalysts were testified as highly effective and repeatable catalysts for the enantioselective epoxidation of styrene and α-methylstyrene.

Keywords
Doubly-immobilized; (salen)Mn(III); Ionic liquid; Enantioselective epoxidation; Recycling
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Highly enantioselective epoxidation of styrene and α-methylstyrene catalyzed by new doubly-immobilized chiral (salen)Mn(III) catalysts
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Publisher
Database: Elsevier - ScienceDirect
Journal: Catalysis Communications - Volume 10, Issue 3, 15 December 2008, Pages 317–320
Authors
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Subjects
Physical Sciences and Engineering Chemical Engineering Catalysis
Get Full-Text Now
Don't Miss Today's Special Offer
Price was $35.95
You save - $31
Price after discount Only $4.95
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Full-text PDF Download
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