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Cathodic C–H electro-activation in ionic liquid: An improved electrochemical method for the conjugate addition of 1,3-dicarbonyl compounds

Paper ID Volume ID Publish Year Pages File Format Full-Text
51940 46859 2008 4 PDF Available
Title
Cathodic C–H electro-activation in ionic liquid: An improved electrochemical method for the conjugate addition of 1,3-dicarbonyl compounds
Abstract

The constant current electrolysis of 1,3-dicarbonyl compounds in 1-ethyl-3-methylimidazolium ethylsulfate (EMIMEtSO4) ionic liquid provided the direct deprotonation of the methylene active functionality to the cathode: the corresponding enolates efficiently underwent to the one-pot Michael addition with activated olefins.

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Cathodic C–H electro-activation in ionic liquid: An improved electrochemical method for the conjugate addition of 1,3-dicarbonyl compounds
Publisher
Database: Elsevier - ScienceDirect
Journal: Catalysis Communications - Volume 10, Issue 3, 15 December 2008, Pages 321–324
Authors
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Subjects
Physical Sciences and Engineering Chemical Engineering Catalysis