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Synthesis of dimethyl carbonate via transesterification of ethylene carbonate with methanol using poly-4-vinyl pyridine as a novel base catalyst

Paper ID Volume ID Publish Year Pages File Format Full-Text
51979 46860 2008 4 PDF Available
Title
Synthesis of dimethyl carbonate via transesterification of ethylene carbonate with methanol using poly-4-vinyl pyridine as a novel base catalyst
Abstract

The synthesis of dimethyl carbonate (DMC) via transesterification of ethylene carbonate with methanol using poly-4-vinyl pyridine (PVP) as a novel, homogeneous, recyclable base catalyst with high yield has been reported. The comparative study for the basicity of PVP was also carried out with other basic polymer such as polyvinylpyrrolidone for DMC synthesis. The catalyst was reused for three consecutive recycles without significant loss of activity/selectivity performance. The effect of different reaction parameters like catalyst loading, reaction time, temperature, CO2 pressure etc. were investigated in detail for the title reaction.

Keywords
Transesterification; Dimethyl carbonate; Ethylene glycol; Poly-4-vinyl pyridine; Methanol
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Synthesis of dimethyl carbonate via transesterification of ethylene carbonate with methanol using poly-4-vinyl pyridine as a novel base catalyst
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Publisher
Database: Elsevier - ScienceDirect
Journal: Catalysis Communications - Volume 9, Issue 9, 15 May 2008, Pages 1928–1931
Authors
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Subjects
Physical Sciences and Engineering Chemical Engineering Catalysis
Get Full-Text Now
Don't Miss Today's Special Offer
Price was $35.95
You save - $31
Price after discount Only $4.95
100% Money Back Guarantee
Full-text PDF Download
Online Support
Any Questions? feel free to contact us