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Highly active and selective catalytic transfer hydrogenolysis of α-methylbenzyl alcohol catalyzed by supported Pd catalyst

Paper ID Volume ID Publish Year Pages File Format Full-Text
51986 46861 2011 6 PDF Available
Title
Highly active and selective catalytic transfer hydrogenolysis of α-methylbenzyl alcohol catalyzed by supported Pd catalyst
Abstract

A novel supported Pd catalyst was synthesized by using plant tannin grafted collagen fiber as the supporting matrix. The as-prepared Pd catalyst was subsequently used for the catalytic transfer hydrogenolysis of α-methylbenzyl alcohol. Due to the fibrous morphology of collagen fiber and the well dispersed Pd nanoparticles anchored by tannins, the as-prepared Pd catalyst showed superior activity for the catalytic transfer hydrogenolysis of α-methylbenzyl alcohol when compared with the Pd catalyst supported on inorganic oxides. Moreover, the as-prepared Pd catalyst can be reused at least 6 times without significant loss of activity and selectivity, suggesting a satisfied reusability.

Graphical abstractFibrous Pd–BT–CF catalyst (a, SEM image) with well dispersed Pd nanoparticles (b, TEM image).Figure optionsDownload full-size imageDownload as PowerPoint slideResearch highlights► Fibrous Pd–BT–CF catalyst with high dispersed Pd nanoparticles. ► Superior activity and reusability for the catalytic transfer hydrogenolysis of α-methylbenzyl alcohol. ► Distinct advantages in catalytic properties as compared with other inorganic oxide supported Pd catalysts.

Keywords
Catalytic transfer hydrogenolysis; Collagen fiber; Plant tannin; Palladium nanoparticles; Activity; Selectivity
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Highly active and selective catalytic transfer hydrogenolysis of α-methylbenzyl alcohol catalyzed by supported Pd catalyst
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Publisher
Database: Elsevier - ScienceDirect
Journal: Catalysis Communications - Volume 12, Issue 13, 26 July 2011, Pages 1177–1182
Authors
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Subjects
Physical Sciences and Engineering Chemical Engineering Catalysis
Get Full-Text Now
Don't Miss Today's Special Offer
Price was $35.95
You save - $31
Price after discount Only $4.95
100% Money Back Guarantee
Full-text PDF Download
Online Support
Any Questions? feel free to contact us