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The esterification of glycerine with lauric acid catalyzed by multi-valent metal salts. Selective formation of mono- and dilaurins

Paper ID Volume ID Publish Year Pages File Format Full-Text
52043 46863 2008 5 PDF Available
Title
The esterification of glycerine with lauric acid catalyzed by multi-valent metal salts. Selective formation of mono- and dilaurins
Abstract

Multi-valent metal salts, such as zirconium, ferric, and aluminum salt hydrates gave high catalytic activity for the esterification of glycerine (GL) with lauric acid (LA) without the solvent. Among them, ZrOCl2 · 8H2O and AlCl3 · 6H2O gave lauric acid monoglyceride (Monolaurin; ML) in high selectivity. Fe2(SO4)3 · nH2O and Zr(SO4)2 · 4H2O gave lauric acid diglyceride (Dilaurin; DL) even in the excess of GL.

Keywords
Multi-valent metal salt; Esterification; Glycerine; Lauric acid; Monolaurin; Dilaurin
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The esterification of glycerine with lauric acid catalyzed by multi-valent metal salts. Selective formation of mono- and dilaurins
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Publisher
Database: Elsevier - ScienceDirect
Journal: Catalysis Communications - Volume 9, Issue 4, 15 March 2008, Pages 511–515
Authors
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Subjects
Physical Sciences and Engineering Chemical Engineering Catalysis
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