fulltext.study @t Gmail

Effective oxidation of alcohols to aldehydes with hydrogen peroxide catalyzed by Pd (OAc)2/SO under solvent-free conditions

Paper ID Volume ID Publish Year Pages File Format Full-Text
52064 46864 2008 5 PDF Available
Title
Effective oxidation of alcohols to aldehydes with hydrogen peroxide catalyzed by Pd (OAc)2/SO under solvent-free conditions
Abstract

With oxygen that was supplied by hydrogen peroxide as oxidant, secondary and primary aliphatic alcohols, primary allylic alcohols could be efficiently oxidized to aldehydes or ketones in high yields in the presence of Pd (OAc)2−sodium oxalate (SO) under solvent-free conditions, it is a high yielding and operationally simple method. Acetic acid is testified to attend the reaction, the acetate ligands are environed to serve two purposes: as a ligand for the PdII center and as a base to deprotonate the Pd-bound alcohol, but acetic acid has not shown in previous bidentate ligands systems, so a mechanism is proposed on the basis of the mechanisms reported by the pioneers.

Keywords
Alcohols; Aldehydes; Hydrogen peroxide; Oxidation; Palladium; Sodium oxalate
First Page Preview
Effective oxidation of alcohols to aldehydes with hydrogen peroxide catalyzed by Pd (OAc)2/SO under solvent-free conditions
Get Full-Text Now
Don't Miss Today's Special Offer
Price was $35.95
You save - $31
Price after discount Only $4.95
100% Money Back Guarantee
Full-text PDF Download
Online Support
Any Questions? feel free to contact us
Publisher
Database: Elsevier - ScienceDirect
Journal: Catalysis Communications - Volume 9, Issue 3, 1 March 2008, Pages 386–390
Authors
, , , ,
Subjects
Physical Sciences and Engineering Chemical Engineering Catalysis
Get Full-Text Now
Don't Miss Today's Special Offer
Price was $35.95
You save - $31
Price after discount Only $4.95
100% Money Back Guarantee
Full-text PDF Download
Online Support
Any Questions? feel free to contact us