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Polyvalent-metal salts of heteropolyacid as efficient heterogeneous catalysts for Friedel–Crafts acylation of arenes with carboxylic acids

Paper ID Volume ID Publish Year Pages File Format Full-Text
52087 46865 2008 4 PDF Available
Title
Polyvalent-metal salts of heteropolyacid as efficient heterogeneous catalysts for Friedel–Crafts acylation of arenes with carboxylic acids
Abstract

Polyvalent-metal (Ti4+, Fe3+, Sn4+, Bi3+, Ru3+) salts of dodecatungstophosphate act as effective heterogeneous catalysts for Friedel–Crafts acylation of aromatics with carboxylic acids. The Fe3+ salt shows high yields and the highest turnover number (2500) reported to date and can be reused without loss of activity, providing one of the greenest route to aromatic ketones.

Keywords
Friedel–Crafts acylation; Heterogeneous catalysts; Polyoxometalates
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Polyvalent-metal salts of heteropolyacid as efficient heterogeneous catalysts for Friedel–Crafts acylation of arenes with carboxylic acids
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Publisher
Database: Elsevier - ScienceDirect
Journal: Catalysis Communications - Volume 9, Issue 6, 31 March 2008, Pages 980–983
Authors
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Subjects
Physical Sciences and Engineering Chemical Engineering Catalysis
Get Full-Text Now
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Price was $35.95
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