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Alkylation of benzene and dichloromethane to diphenylmethane with acidic ionic liquids

Paper ID Volume ID Publish Year Pages File Format Full-Text
52122 46865 2008 5 PDF Available
Title
Alkylation of benzene and dichloromethane to diphenylmethane with acidic ionic liquids
Abstract

Liquid-phase alkylation of benzene and dichloromethane as alkylating agent to diphenylmethane with acidic ionic liquids such as Et3NHCl–AlCl3, Et3NHCl–FeCl3, Et3NHCl–ZnCl2, Et3NHCl–CuCl2, Et3NHCl–SnCl2 and Et3NHCl–SnCl4 was investigated. The results showed that Et3NHCl–AlCl3 proved to be superior catalytic activity to other five ionic liquids with the conversion of 83.8% and the selectivity of 86.3% at a moderate temperature. Meanwhile, the influence of reaction conditions on the reaction, the reaction kinetics and the usability of the catalyst were explored.

Keywords
Diphenylmethane; Benzene; Dichloromethane; Ionic liquid; Alkylation
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Alkylation of benzene and dichloromethane to diphenylmethane with acidic ionic liquids
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Publisher
Database: Elsevier - ScienceDirect
Journal: Catalysis Communications - Volume 9, Issue 6, 31 March 2008, Pages 1173–1177
Authors
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Subjects
Physical Sciences and Engineering Chemical Engineering Catalysis
Get Full-Text Now
Don't Miss Today's Special Offer
Price was $35.95
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Price after discount Only $4.95
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