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Oxidative cleavage of vic-diols catalyzed by manganese (III) complexes in ionic liquids

Paper ID Volume ID Publish Year Pages File Format Full-Text
52141 46865 2008 4 PDF Available
Title
Oxidative cleavage of vic-diols catalyzed by manganese (III) complexes in ionic liquids
Abstract

The oxidative cleavage of vicinal diols allows the selective oxidation of diols in order to obtain aldehydes or ketones. In this work we present a novel catalytic system based on MnIII(salen) complexes dissolved in ionic liquids that allows high efficiency with low environmental impact in the oxidative cleavage of ethyleneglycol, pinacol, benzopinacol and hydrobenzoin. The use of ionic liquids in this reaction shows a positive effect of the solvent in the efficiency of the MnIII catalysts (increase of the yield in ionic liquids: 10–60%).

Keywords
Oxidative cleavage; Ionic liquids; Salen; Mn(III)-catalyst; Vic-diol
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Oxidative cleavage of vic-diols catalyzed by manganese (III) complexes in ionic liquids
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Publisher
Database: Elsevier - ScienceDirect
Journal: Catalysis Communications - Volume 9, Issue 6, 31 March 2008, Pages 1282–1285
Authors
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Subjects
Physical Sciences and Engineering Chemical Engineering Catalysis
Get Full-Text Now
Don't Miss Today's Special Offer
Price was $35.95
You save - $31
Price after discount Only $4.95
100% Money Back Guarantee
Full-text PDF Download
Online Support
Any Questions? feel free to contact us