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N-Iodosuccinimide (NIS) a novel and effective catalyst for the cyanosilylation of aldehydes under mild reaction conditions

Paper ID Volume ID Publish Year Pages File Format Full-Text
52151 46865 2008 4 PDF Available
Title
N-Iodosuccinimide (NIS) a novel and effective catalyst for the cyanosilylation of aldehydes under mild reaction conditions
Abstract

An efficient protocol for the addition of TMSCN to aldehydes in CH2Cl2 by employing 0.5 mol% of N-iodosuccinimide (NIS) as the catalyst is presented. A variety of aldehydes have been converted into the corresponding trimethylsilylethers within 15 min in excellent yield (up to 99%) under mild conditions.

Keywords
Cyanosilylation; Aldehydes; N-Iodosuccinimide; Cyanohydrins
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N-Iodosuccinimide (NIS) a novel and effective catalyst for the cyanosilylation of aldehydes under mild reaction conditions
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Publisher
Database: Elsevier - ScienceDirect
Journal: Catalysis Communications - Volume 9, Issue 6, 31 March 2008, Pages 1342–1345
Authors
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Subjects
Physical Sciences and Engineering Chemical Engineering Catalysis
Get Full-Text Now
Don't Miss Today's Special Offer
Price was $35.95
You save - $31
Price after discount Only $4.95
100% Money Back Guarantee
Full-text PDF Download
Online Support
Any Questions? feel free to contact us