fulltext.study @t Gmail

Selective oxidation of allylic alcohols catalyzed by silver exchanged molybdovanado phosphoric acid catalyst in the presence of molecular oxygen

Paper ID Volume ID Publish Year Pages File Format Full-Text
52161 46865 2008 5 PDF Available
Title
Selective oxidation of allylic alcohols catalyzed by silver exchanged molybdovanado phosphoric acid catalyst in the presence of molecular oxygen
Abstract

The Keggin type 12-molybdophosphoric acid is modified by incorporation of vanadium or silver and used as a heterogeneous catalyst for selective oxidation using molecular oxygen as an oxidant. A variety of aromatic and aliphatic primary and secondary allylic alcohols are used as reactants to convert them into their corresponding aldehydes and ketones. Good to excellent yields are achieved when 12-molybdophosphoric acid contains both vanadium and silver. The high catalytical activity might be due to a synergistic effect between silver cationic centers and the redox active vanadium centers. The present catalyst is reusable without any appreciable loss in activity.

Keywords
Silver exchanged molybdovanado phosphoric acid; Allylic alcohols; Molecular oxygen; Oxidation
First Page Preview
Selective oxidation of allylic alcohols catalyzed by silver exchanged molybdovanado phosphoric acid catalyst in the presence of molecular oxygen
Get Full-Text Now
Don't Miss Today's Special Offer
Price was $35.95
You save - $31
Price after discount Only $4.95
100% Money Back Guarantee
Full-text PDF Download
Online Support
Any Questions? feel free to contact us
Publisher
Database: Elsevier - ScienceDirect
Journal: Catalysis Communications - Volume 9, Issue 6, 31 March 2008, Pages 1389–1393
Authors
, , , , ,
Subjects
Physical Sciences and Engineering Chemical Engineering Catalysis
Get Full-Text Now
Don't Miss Today's Special Offer
Price was $35.95
You save - $31
Price after discount Only $4.95
100% Money Back Guarantee
Full-text PDF Download
Online Support
Any Questions? feel free to contact us