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Ru-catalyzed metathesis of octadienylether xyloside

Paper ID Volume ID Publish Year Pages File Format Full-Text
52166 46865 2008 4 PDF Available
Title
Ru-catalyzed metathesis of octadienylether xyloside
Abstract

The reaction of the octadienylether of xylosyle and of its peracetylated form in the presence of Grubbs catalysts has led to O-allyl carbohydrates, and from the protected carbohydrate, to the bolaform with a C4 tether. The concomitant formation of cyclopentene, highlighted from analysis of the crude reaction by mass spectroscopy, led to propose a mechanistic scheme involving both double bonds of the substrate.

Keywords
Metathesis; Cleavage; Ruthenium; Xylose; Mechanism
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Publisher
Database: Elsevier - ScienceDirect
Journal: Catalysis Communications - Volume 9, Issue 6, 31 March 2008, Pages 1414–1417
Authors
, , , ,
Subjects
Physical Sciences and Engineering Chemical Engineering Catalysis
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Price was $35.95
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