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Synthesis of ethyl tert-butyl ether with tert-butyl alcohol and ethanol on various ion exchange resin catalysts

Paper ID Volume ID Publish Year Pages File Format Full-Text
52243 46867 2008 7 PDF Available
Title
Synthesis of ethyl tert-butyl ether with tert-butyl alcohol and ethanol on various ion exchange resin catalysts
Abstract

Heterogeneous catalytic synthesis of ETBE with tert-butyl alcohol (TBA) and ethanol (EtOH) using seven ion exchange resins has been studied. After characterization of catalysts, batch kinetic studies were conducted to sort out the most suitable catalyst based on TBA conversion and ETBE selectivity. Optimum operating conditions found were 343 K temperature; 1:2 feed mole ratio (TBA:EtOH), and 10% catalyst loading. Kinetic modeling for the most suitable catalyst CT-145H was done using heterogeneous and quasi-homogeneous models, but latter fit well to experimental data.

Keywords
ETBE synthesis; Ion exchange resins; Heterogeneous catalysis; Kinetic modeling
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Synthesis of ethyl tert-butyl ether with tert-butyl alcohol and ethanol on various ion exchange resin catalysts
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Publisher
Database: Elsevier - ScienceDirect
Journal: Catalysis Communications - Volume 9, Issue 5, 20 March 2008, Pages 721–727
Authors
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Subjects
Physical Sciences and Engineering Chemical Engineering Catalysis
Get Full-Text Now
Don't Miss Today's Special Offer
Price was $35.95
You save - $31
Price after discount Only $4.95
100% Money Back Guarantee
Full-text PDF Download
Online Support
Any Questions? feel free to contact us