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A binuclear chloride-bridged organopalladium(II) complex and its role in Heck reaction

Paper ID Volume ID Publish Year Pages File Format Full-Text
52262 46867 2008 5 PDF Available
Title
A binuclear chloride-bridged organopalladium(II) complex and its role in Heck reaction
Abstract

The arylation reaction between electron-deficient or electron-rich alkenes and several aryl bromides and heteroaryl bromides in the presence of the complex [Pd2Cl2{(C6H5)2PO···H···OP(C6H5)2}2] (1) shows good activity and outstanding yields. The reaction tolerates several functionalities and excellent regiocontrol with electron-deficient alkenes. Taking into account the easy metal-template synthesis and remarkable air stability of this complex, it is a good example to understand the diphenylphosphinito complexes utility in catalysis.

Keywords
Heck reaction; Diphenylphosphinito; Palladium complex; C–C coupling reactions; Homogeneous catalysis
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A binuclear chloride-bridged organopalladium(II) complex and its role in Heck reaction
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Publisher
Database: Elsevier - ScienceDirect
Journal: Catalysis Communications - Volume 9, Issue 5, 20 March 2008, Pages 826–830
Authors
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Subjects
Physical Sciences and Engineering Chemical Engineering Catalysis
Get Full-Text Now
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Price was $35.95
You save - $31
Price after discount Only $4.95
100% Money Back Guarantee
Full-text PDF Download
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