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Isomerization reactions of n-hexane on partially reduced MoO3/TiO2

Paper ID Volume ID Publish Year Pages File Format Full-Text
52266 46867 2008 6 PDF Available
Title
Isomerization reactions of n-hexane on partially reduced MoO3/TiO2
Abstract

Isomerization of n-hexane on partially reduced MoO3 deposited on TiO2 was carried out using different masses of the catalyst. Consistent catalytic behaviour in terms of conversion and isomerization selectivity was observed regardless of the mass of the catalyst. A typical conversion of 80% and 90% of selectivity in isomerization products was obtained at 623 K, 0.7 h−1 LHSV and 15 bar hydrogen pressure. The major isomerization products are 2MP and 3MP present at the thermodynamic equilibrium ratio. Di-branched 2,2-DMB and 2,3-DMB were also obtained in the range of 18% of the isomerization products. The products distribution is comparable to that reported for Pt based catalysts. No changes were observed in the catalyst activity following its exposure to the hydrocarbon reactant for 60 days.

Keywords
MoO3; TiO2; Bifunctional catalysis; Isomerization of n-hexane; LHSV
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Isomerization reactions of n-hexane on partially reduced MoO3/TiO2
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Publisher
Database: Elsevier - ScienceDirect
Journal: Catalysis Communications - Volume 9, Issue 5, 20 March 2008, Pages 847–852
Authors
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Subjects
Physical Sciences and Engineering Chemical Engineering Catalysis
Get Full-Text Now
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Price was $35.95
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