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Synthesis of acetic acid and acetic anhydride from methanol carbonylation with polymer supported rhodium catalyst

Paper ID Volume ID Publish Year Pages File Format Full-Text
52267 46867 2008 6 PDF Available
Title
Synthesis of acetic acid and acetic anhydride from methanol carbonylation with polymer supported rhodium catalyst
Abstract

Novel porous spherules fabricated via crosslinking copolymerization of 2-vinyl pyridine and ethylene glycol diacrylate and the subsequent formation of chelate complex with [Rh(CO)2Cl2]− were reported in this paper. The complex is well swelled in the reaction medium. Advantages of this catalyst lied in the fact that it could rapidly catalyze carbonylation of methanol to acetic acid with high selectivity and directly formed some acetic anhydride under mild conditions (⩾140 °C). In addition, occurrence of water gas shift reaction during the process is hardly observable.

Keywords
Methanol carbonylation; Rhodium/polymer catalyst; Catalytic activity
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Synthesis of acetic acid and acetic anhydride from methanol carbonylation with polymer supported rhodium catalyst
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Publisher
Database: Elsevier - ScienceDirect
Journal: Catalysis Communications - Volume 9, Issue 5, 20 March 2008, Pages 853–858
Authors
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Subjects
Physical Sciences and Engineering Chemical Engineering Catalysis
Get Full-Text Now
Don't Miss Today's Special Offer
Price was $35.95
You save - $31
Price after discount Only $4.95
100% Money Back Guarantee
Full-text PDF Download
Online Support
Any Questions? feel free to contact us