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Comparison of the conventional impregnation method using ammonium heptamolybdate with a simple route to silica-supported molybdenum(VI) materials

Paper ID Volume ID Publish Year Pages File Format Full-Text
52312 46869 2007 5 PDF Available
Title
Comparison of the conventional impregnation method using ammonium heptamolybdate with a simple route to silica-supported molybdenum(VI) materials
Abstract

Silica-supported molybdenum oxide materials have been prepared by using the ability of molybdenum oxoperoxo complexes to interact with the surface hydroxyl groups of the support, which after calcination, have a highly dispersed MoOx/SiO2 structure, and lead to leach-resistant catalysts; with a polyoxo precursor, (NH4)6[Mo7O24] · 4H2O, there is a formation of MoO3 clusters and a weaker MoO3/SiO2 interaction.

Keywords
Epoxidation; Molybdenum; Mesoporous materials; H2O2
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Comparison of the conventional impregnation method using ammonium heptamolybdate with a simple route to silica-supported molybdenum(VI) materials
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Publisher
Database: Elsevier - ScienceDirect
Journal: Catalysis Communications - Volume 8, Issue 10, October 2007, Pages 1447–1451
Authors
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Subjects
Physical Sciences and Engineering Chemical Engineering Catalysis
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Price was $35.95
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