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Investigation of catalytic activity of cobalt–Schiff base complex covalently linked to the polyoxometalate in the alkene and benzyl halide oxidation with hydrogen peroxide

Paper ID Volume ID Publish Year Pages File Format Full-Text
52338 46870 2008 5 PDF Available
Title
Investigation of catalytic activity of cobalt–Schiff base complex covalently linked to the polyoxometalate in the alkene and benzyl halide oxidation with hydrogen peroxide
Abstract

The catalytic activity of a hybrid compound Co(salen)–POM (1) consisting of cobalt(salen) [salen = N,N′-bis(salicylidene)ethylenediamine] complex covalently linked to a Keggin type polyoxometalate (POM) was studied, for the first time, in the oxidation of various olefins in acetonitrile, using hydrogen peroxide as an oxygen source. The complex (1) can catalyze oxidation of various olefins including non-activated terminal olefins. The effect of other parameters such as solvent, oxidant and temperature were also investigated. The selective oxidation of benzyl halides to their corresponding carbonyl compounds by complex (1), as catalyst, was also examined at room temperature.

Keywords
Co(salen); Olefin oxidation; Polyoxometalate; Benzyl halides; Hydrogen peroxide
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Investigation of catalytic activity of cobalt–Schiff base complex covalently linked to the polyoxometalate in the alkene and benzyl halide oxidation with hydrogen peroxide
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Publisher
Database: Elsevier - ScienceDirect
Journal: Catalysis Communications - Volume 9, Issue 2, February 2008, Pages 219–223
Authors
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Subjects
Physical Sciences and Engineering Chemical Engineering Catalysis
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Price was $35.95
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