fulltext.study @t Gmail

Supported RuB amorphous alloy mediated 1 atm hydrogenation of carbonyl compounds under ambient temperature

Paper ID Volume ID Publish Year Pages File Format Full-Text
52366 46872 2008 8 PDF Available
Title
Supported RuB amorphous alloy mediated 1 atm hydrogenation of carbonyl compounds under ambient temperature
Abstract

Tin promoted RuB amorphous alloy supported on SiO2 was prepared by a novel reductant impregnation method for the hydrogenation of carbonyl compounds to the corresponding alcohol under atmospheric H2 and ambient temperature. The as-prepared Ru–Sn–B/SiO2 catalyst presented high activity for hydrogenation of carbonyl compounds even under atmospheric H2. The TEM images showed that addition of tin improved the dispersion of RuB particles, and then significantly increased the conversion of carbonyl compounds. Based on the XPS spectra and catalytic performance, tin in Ru–Sn–B/SiO2 catalyst was supposed to play a role of adsorbing and activating the CO bond of carbonyl group during the hydrogenation.

Keywords
RuB catalyst; Amorphous alloy; Tin; Carbonyl group; Hydrogenation
First Page Preview
Supported RuB amorphous alloy mediated 1 atm hydrogenation of carbonyl compounds under ambient temperature
Get Full-Text Now
Don't Miss Today's Special Offer
Price was $35.95
You save - $31
Price after discount Only $4.95
100% Money Back Guarantee
Full-text PDF Download
Online Support
Any Questions? feel free to contact us
Publisher
Database: Elsevier - ScienceDirect
Journal: Catalysis Communications - Volume 9, Issue 1, January 2008, Pages 27–34
Authors
, , , ,
Subjects
Physical Sciences and Engineering Chemical Engineering Catalysis
Get Full-Text Now
Don't Miss Today's Special Offer
Price was $35.95
You save - $31
Price after discount Only $4.95
100% Money Back Guarantee
Full-text PDF Download
Online Support
Any Questions? feel free to contact us