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Promoting effect of transition metal salts on rhodium catalyzed methanol carbonylation

Paper ID Volume ID Publish Year Pages File Format Full-Text
52409 46873 2006 4 PDF Available
Title
Promoting effect of transition metal salts on rhodium catalyzed methanol carbonylation
Abstract

Some transition metal chlorides were used as promoters for homogeneous rhodium catalyzed methanol carbonylation. The experiments were carried out at low water conditions. All of the catalysts with the promoters demonstrate better catalytic activity than the pristine Monsanto catalyst. Ni, Fe and Co chlorides are most efficient promoters, among which Ni manifest the best performance in accelerating the catalytic rate. All the experiments promoted by such promoters demonstrate good stability and catalytic selectivity.

Keywords
Methanol carbonylation; Rhodium catalyst; Transition metal salts; Catalytic activity
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Promoting effect of transition metal salts on rhodium catalyzed methanol carbonylation
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Publisher
Database: Elsevier - ScienceDirect
Journal: Catalysis Communications - Volume 7, Issue 11, November 2006, Pages 885–888
Authors
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Subjects
Physical Sciences and Engineering Chemical Engineering Catalysis
Get Full-Text Now
Don't Miss Today's Special Offer
Price was $35.95
You save - $31
Price after discount Only $4.95
100% Money Back Guarantee
Full-text PDF Download
Online Support
Any Questions? feel free to contact us