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Anchoring manganese acetylacetonate complex on MCM-41: Catalytic testing on limonene oxidation

Paper ID Volume ID Publish Year Pages File Format Full-Text
52429 46874 2007 7 PDF Available
Title
Anchoring manganese acetylacetonate complex on MCM-41: Catalytic testing on limonene oxidation
Abstract

This work reports the results of limonene oxidation in the liquid phase, over manganese acetylacetonate anchored onto MCM-41. Diluted t-butyl hydroperoxide is used as oxidant. Limonene oxide, carveol and carvone are formed, but the main product obtained is a polymer. The preservation of the MCM-41 channel system upon anchoring was checked by transmission electron microscopy (TEM), X-ray diffraction and nitrogen adsorption analysis. The complex anchoring was succeeded, since the catalyst could be used in four consecutive experiments. The maximum TOF values obtained for each run are similar and no significant metal complex leaching was observed (3% after the 4th run).

Keywords
Manganese Schiff base; MCM-41; Epoxidation; Limonene
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Publisher
Database: Elsevier - ScienceDirect
Journal: Catalysis Communications - Volume 8, Issue 9, September 2007, Pages 1366–1372
Authors
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Subjects
Physical Sciences and Engineering Chemical Engineering Catalysis
Get Full-Text Now
Don't Miss Today's Special Offer
Price was $35.95
You save - $31
Price after discount Only $4.95
100% Money Back Guarantee
Full-text PDF Download
Online Support
Any Questions? feel free to contact us