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Alumina supported copper nanoparticles for aziridination and cyclopropanation reactions

Paper ID Volume ID Publish Year Pages File Format Full-Text
52464 46875 1968 6 PDF Available
Title
Alumina supported copper nanoparticles for aziridination and cyclopropanation reactions
Abstract

Alumina supported copper (Cu–Al2O3) nanoparticles were prepared and applied for the aziridination of olefins employing [N-(p-tolylsulfonyl)imino]phenyliodinane (PhI = NTs) as nitrene source to afford the corresponding 3-membered cyclic compounds in moderate to excellent yields. Cyclopropanation of several olefins was also carried out by using Cu–Al2O3 nanoparticles and ethyl diazoacetate as a carbene source. The catalyst was recovered by simple centrifugation and reused for four cycles.

Keywords
Alumina; Copper nanoparticles; Aziridination; Cyclopropanation; Reusability
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Alumina supported copper nanoparticles for aziridination and cyclopropanation reactions
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Publisher
Database: Elsevier - ScienceDirect
Journal: Catalysis Communications - Volume 8, Issue 12, December 2007, Pages 1963–1968
Authors
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Subjects
Physical Sciences and Engineering Chemical Engineering Catalysis
Get Full-Text Now
Don't Miss Today's Special Offer
Price was $35.95
You save - $31
Price after discount Only $4.95
100% Money Back Guarantee
Full-text PDF Download
Online Support
Any Questions? feel free to contact us