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On the location of different titanium sites in Ti–OMS-2 and their catalytic role in oxidation of styrene

Paper ID Volume ID Publish Year Pages File Format Full-Text
52473 46875 2011 5 PDF Available
Title
On the location of different titanium sites in Ti–OMS-2 and their catalytic role in oxidation of styrene
Abstract

Octahedral manganese oxide molecular sieves (OMS-2) modified by impregnation of TiO2 exhibit a higher catalytic activity for oxidation of styrene with tert-butylhydroperoxide in comparison to titanium-incorporated OMS-2, where the styrene conversions were ca. 70% and 45–50%, respectively. The framework of titanium species has no effect on the enhancement of catalytic activity, while the non-framework of titanium species induces a synergetic effect that enhances the oxidation of styrene with tert-butylhydroperoxide.

Keywords
Titanium-incorporated octahedral manganese oxide molecular sieves; Non-framework titanium; Oxidation of styrene
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On the location of different titanium sites in Ti–OMS-2 and their catalytic role in oxidation of styrene
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Publisher
Database: Elsevier - ScienceDirect
Journal: Catalysis Communications - Volume 8, Issue 12, December 2007, Pages 2007–2011
Authors
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Subjects
Physical Sciences and Engineering Chemical Engineering Catalysis
Get Full-Text Now
Don't Miss Today's Special Offer
Price was $35.95
You save - $31
Price after discount Only $4.95
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Full-text PDF Download
Online Support
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