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Significant yield improvement in the stereoselective synthesis of allyl cyanides from Baylis–Hillman derivatives in aqueous medium under the influence of the phase-transfer catalyst ☆

Paper ID Volume ID Publish Year Pages File Format Full-Text
52480 46875 2007 5 PDF Available
Title
Significant yield improvement in the stereoselective synthesis of allyl cyanides from Baylis–Hillman derivatives in aqueous medium under the influence of the phase-transfer catalyst ☆
Abstract

The nucleophilic reaction of NaCN with the acetyl derivative of Baylis–Hillman adducts in the presence of a phase-transfer catalyst in aqueous medium stereoselectively affords the corresponding allyl cyanides in a short period and excellent yields.

Keywords
Baylis–Hillman; Allyl cyanide; NaCN; Phase-transfer catalyst; Water
First Page Preview
Significant yield improvement in the stereoselective synthesis of allyl cyanides from Baylis–Hillman derivatives in aqueous medium under the influence of the phase-transfer catalyst ☆
Publisher
Database: Elsevier - ScienceDirect
Journal: Catalysis Communications - Volume 8, Issue 12, December 2007, Pages 2048–2052
Authors
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Subjects
Physical Sciences and Engineering Chemical Engineering Catalysis