fulltext.study @t Gmail

Highly efficient chemoselective catalytic hydrogenation of diaryl substituted α,β-unsaturated nitriles/carbonyls using homogeneous Pd(OAc)2/PPh3 catalyst

Paper ID Volume ID Publish Year Pages File Format Full-Text
52483 46875 2007 5 PDF Available
Title
Highly efficient chemoselective catalytic hydrogenation of diaryl substituted α,β-unsaturated nitriles/carbonyls using homogeneous Pd(OAc)2/PPh3 catalyst
Abstract

α,β-unsaturated nitriles are chemoselectively hydrogenated to corresponding saturated nitriles with Pd(OAc)2/PPh3 as a homogeneous catalytic system using atmospheric pressure of molecular hydrogen. Various parameters like catalyst concentration, role of solvents, variation in the reaction temperature were screened and optimized reaction conditions were successfully used for chemoselective hydrogenation of other diaryl substituted α,β-unsaturated nitriles. The present catalytic system have also been used for hydrogenation of α,β-unsaturated carbonyls at atmospheric pressure of hydrogen.

Keywords
Unsaturated nitrile; Chemoselectivity; Homogeneous hydrogenation; Palladium; P-ligands
First Page Preview
Highly efficient chemoselective catalytic hydrogenation of diaryl substituted α,β-unsaturated nitriles/carbonyls using homogeneous Pd(OAc)2/PPh3 catalyst
Get Full-Text Now
Don't Miss Today's Special Offer
Price was $35.95
You save - $31
Price after discount Only $4.95
100% Money Back Guarantee
Full-text PDF Download
Online Support
Any Questions? feel free to contact us
Publisher
Database: Elsevier - ScienceDirect
Journal: Catalysis Communications - Volume 8, Issue 12, December 2007, Pages 2064–2068
Authors
, , , ,
Subjects
Physical Sciences and Engineering Chemical Engineering Catalysis
Get Full-Text Now
Don't Miss Today's Special Offer
Price was $35.95
You save - $31
Price after discount Only $4.95
100% Money Back Guarantee
Full-text PDF Download
Online Support
Any Questions? feel free to contact us