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A promotion effect of alkaline-earth chloride on N-hydroxyphthalimide-catalyzed aerobic oxidation of hydrocarbons

Paper ID Volume ID Publish Year Pages File Format Full-Text
52528 46876 2009 4 PDF Available
Title
A promotion effect of alkaline-earth chloride on N-hydroxyphthalimide-catalyzed aerobic oxidation of hydrocarbons
Abstract

Alkaline-earth chloride was used as an effective promoter for the aerobic oxidation of hydrocarbons catalyzed by N-hydroxyphthalimide (NHPI). Various hydrocarbons including benzylic compounds, cycloalkene, and cycloalkane can be easily oxygenated with molecular oxygen catalyzed by the alkaline-earth chloride/NHPI system. Ultraviolet–visible (UV–vis) spectroscopy and Fourier transform infrared (FT-IR) spectroscopy were employed to investigate the essential of the promotion effect of alkaline-earth chloride. The results revealed that alkaline-earth chloride facilitated the generation of the active species phthalimide-N-oxyl (PINO) radical which further catalyzed the oxidation of hydrocarbons.

Keywords
Alkaline-earth chloride; N-hydroxyphthalimide; Aerobic oxidation; Hydrocarbons
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A promotion effect of alkaline-earth chloride on N-hydroxyphthalimide-catalyzed aerobic oxidation of hydrocarbons
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Publisher
Database: Elsevier - ScienceDirect
Journal: Catalysis Communications - Volume 11, Issue 3, 25 November 2009, Pages 171–174
Authors
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Subjects
Physical Sciences and Engineering Chemical Engineering Catalysis
Get Full-Text Now
Don't Miss Today's Special Offer
Price was $35.95
You save - $31
Price after discount Only $4.95
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