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Eu(OTf)3-catalyzed oxidation of 5-alkylidene-4,5-dihydrofurans: A new approach to functionalized furylhydroperoxides

Paper ID Volume ID Publish Year Pages File Format Full-Text
52559 46877 2007 4 PDF Available
Title
Eu(OTf)3-catalyzed oxidation of 5-alkylidene-4,5-dihydrofurans: A new approach to functionalized furylhydroperoxides
Abstract

Here reported is an unusual catalytic ability of Eu(OTf)3 in the oxidative conversion of 5-alkylidene-4,5-dihydrofuran derivatives in the corresponding furylhydroperoxides with tert-butyl hydroperoxide. Furthermore, an enantioselective process of disproportionation of furylhydroperoxides has been highlighted in the presence of the Jacobsen’s catalyst (S,S)-(+)-N,N′-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminomanganese(III) chloride.

Keywords
Eu(III); Oxidation; Hydroperoxides; Jacobsen’s catalyst; Furylalcohols
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Eu(OTf)3-catalyzed oxidation of 5-alkylidene-4,5-dihydrofurans: A new approach to functionalized furylhydroperoxides
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Publisher
Database: Elsevier - ScienceDirect
Journal: Catalysis Communications - Volume 8, Issue 11, November 2007, Pages 1655–1658
Authors
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Subjects
Physical Sciences and Engineering Chemical Engineering Catalysis
Get Full-Text Now
Don't Miss Today's Special Offer
Price was $35.95
You save - $31
Price after discount Only $4.95
100% Money Back Guarantee
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Online Support
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