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Synthesis of isoalkanes over Fe–Zn–Zr/HY composite catalyst through carbon dioxide hydrogenation

Paper ID Volume ID Publish Year Pages File Format Full-Text
52569 46877 2007 4 PDF Available
Title
Synthesis of isoalkanes over Fe–Zn–Zr/HY composite catalyst through carbon dioxide hydrogenation
Abstract

The reaction path of isoalkanes formation via CO2 hydrogenation was studied over the Fe–Zn–Zr/HY composite catalyst, which gives high selectivity to isoalkanes. The results indicate that the reverse water–gas shift reaction is not the indispensable step for the synthesis of hydrocarbons. And i-C4 (iso-butane) is formed from propylene and methanol through MTG (methanol to gasoline) reaction and i-C5 (iso-pentane) obtained from the reaction of C2 and C3 through the additive dimerization. A part of C1, C4 is formed on the sole Fe–Zn–Zr catalyst from methanol for the CO2 hydrogenation over Fe–Zn–Zr/HY composite catalyst.

Keywords
Synthesis; Isoalkanes; Hydrogenation; Carbon dioxide
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Synthesis of isoalkanes over Fe–Zn–Zr/HY composite catalyst through carbon dioxide hydrogenation
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Publisher
Database: Elsevier - ScienceDirect
Journal: Catalysis Communications - Volume 8, Issue 11, November 2007, Pages 1711–1714
Authors
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Subjects
Physical Sciences and Engineering Chemical Engineering Catalysis
Get Full-Text Now
Don't Miss Today's Special Offer
Price was $35.95
You save - $31
Price after discount Only $4.95
100% Money Back Guarantee
Full-text PDF Download
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